|本期目录/Table of Contents|

[1]赵彩霞,李新华.铁骨架配合物凝胶的合成、表征及催化性能[J].温州职业技术学院学报,2013,04:64-69.
 ZHAO Caixia,LI Xinhua.Synthesis, Characterization and Catalytic Property of Iron Skeleton Complexes Gels[J].Journal of Wenzhou Vocational and Technical College,2013,04:64-69.
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铁骨架配合物凝胶的合成、表征及催化性能(PDF)

《温州职业技术学院学报》[ISSN:1006-6977/CN:61-1281/TN]

期数:
2013年04期
页码:
64-69
栏目:
应用技术
出版日期:
2013-12-15

文章信息/Info

Title:
Synthesis, Characterization and Catalytic Property of Iron Skeleton Complexes Gels
作者:
赵彩霞;李新华
温州大学 化学与材料工程学院,浙江 温州 325035
Author(s):
ZHAO Caixia LI Xinhua
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, China
关键词:
骨架配合物凝胶催化
Keywords:
Skeleton complex Gels Catalysis
分类号:
O614
DOI:
-
文献标识码:
A
摘要:
以铁盐和1,3,5- 均苯三甲酸为原料,按照一定的配比在不同的溶剂中合成一系列铁骨架配合物凝 胶,并进行SEM 和红外光谱(IR)表征;以吡啶和苯硼酸的Suzuki-Miyaura 交叉偶联反应及苯乙炔和芳烃的加成 反应为例,研究铁骨架配合物凝胶催化性能。结果表明,以合成的铁骨架配合物凝胶作催化剂,反应产率高,廉 价且绿色环保,无需昂贵的配体、强碱环境、高温及气体氛围等条件。
Abstract:
With ferric salt and 1, 3, 5-benzenetricarboxylic acid as raw materials, a series of iron skeleton complex gel is synthesized in different solvent according to a certain ratio and the gels are characterized by SEM images and IR spectra. The catalytic properties of iron skeleton complex gels are discussed based on Suzuki-Miyaura cross-coupling reaction of pyridine and phenylboronic acid as well as the addition reaction of arene and alkyne. The result shows that without expensive ligand, alkali environment, high temperature and gas atmosphere, it is high in reaction efficiency, low in price and environment-friendly with the synthesized iron skeleton complex gel as the catalyzer.

参考文献/References

[1] Stock N,Biswas S.Synthesis of metal-organic frameworks(MOFs):routes to various MOF topologies,morphologies,and composites[J].Chemical Reviews,2012,112(2):933-969.
[2] Pazf A A,Klinowski J,Vilela S M F,et al.Ligand design for functional metal-organic frameworks[J].Chemical Society Reviews,2012,41(3):1088-1110.
[3] Li J R,Sculiey J,Zhou H C.Metal-organic frameworks for separations[J].Chemical Reviews,2012,112(2):869-932.
[4] Geng J C,Liu L W,Xiao S L,et al.Two 2D Cobalt(II)coordination frameworks with unusual inodal network topology: synthesis,structures,and catalytic properties[J].Transition Metal Chemistry,2013,38(2):143-148.
[5] Park T H,Hickman A J,Kohk,et al.Highly Dispersed Palladium(II)in a defective metal organic framework:application to CH activation and functionalization[J].Journal of the American Chemical Society,2011,133(50):20138-20141.
[6] Corma A,Garcia H,Llabrés I Xamena F X.Engineering metal organic frameworks for heterogeneous catalysis[J].Chemical Reviews,2010,110(8):4606-4655.
[7] Farrusseng D,Aguado S,Pinel C.Metal-organic frameworks:opportunities for catalysis[J].Angewandte Chemie(International ed.in English),2009,48(41):7502-7513.
[8] Meilikhov M,Yusenko K,Esken D,et al.Metals@MOFs-Loading MOFs with metal nanoparticles for hybrid functions[J]. European Journal of Inorganic Chemistry,2010(24):3701-3714.
[9] Juan-alcaniz J,Gascon J,Kapteiji F.Metal-organic frameworks as scaffolds for the encapsulation of active species: state of the art and future perspectives[J].Journal of Materials Chemistry,2012,22(20):10102-10118.
[10] Pan Y Y,Yuan B Z,Li Y W,et al.Multifunctional catalysis by Pd@MIL-101:one-step synthesis of methyl isobutyl ketone over palladium nanoparticles deposited on a metal organic framework[J].Chemical Communication,2010,46(13):2280-2282.
[11] Cirujano F G,Llabrés I Xamena F X,Corma A.MOFs as multifunctional catalysts:one-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst[J].Dalton Transaction,2012,41(14):4249-4254.
[12] Luz I,León A,Boronat M,et al.Selective aerobic oxidation of activated alkanes with MOFs and their use for epoxidation of olefins with oxygen in a tandem reaction[J].Catalysis Science Technology,2013,3(2):371-379.
[13] Roubeau O,Colin A,Schmitt V,et al.Thermoreversible gels as magneto-optical switches[J].Angewandte Chemie International Edition,2004,43(25):3283-3286.
[14] Yin J F,Yang G L,Wang H L,et al.Macroporous polymer monoliths fabricated by using a metal-organic coordination gel template[J].Chemical Communication,2007,(44):4614-4616.
[15] Liu Y R,He L S,Zhang J Y,et al.Evolution of spherical assemblies to fibrous networked Pd(II)gels from a pyridine-based tripodal ligand and their catalytic property[J].Chemistry of Materials,2009,21(3):557-563.
[16] Graf T A,Anaerson T K,Bowden N B.Extended lifetimes of gold(II)chloride catalysts using copper(II)chloride and 2,2,6, 6-tetramethylpiperidine 1-oxyl(TEMPO)[J].Advanced Synthesis & Catalysis,2011,353(7):1033-1038.
[17] Zhang J Y,Wang X B,He L S,et al.Metal-organic gels as functionalisable supports for catalysis[J].New Journal of Chemistry, 2009,33(5):1070-1075.
[18] Chen S Y,Wen J,Zhang J,et al.Iron-mediated direct arylation of unactivated arenes[J].Angewandte Chemie International Edition,2008,47(46):8897-8900.
[19] Zou T,Pi S S,Li J H.FeCl3-catalyzed 1,2-addition reaction of aryl aldehydes with arylboronic acids[J].Organic Letters, 2009,11(2):453-456.
[20] Wen J,Qin S,Ma L F,et al.Iron-mediated direct Suzuki-miyaura reaction:a new method for the ortho-arylation of pyrrole and pyridine[J].Organic Letters,2010,12(12):2694-2697.
[21] Bhilare S V,Darvatkar N B,Sslunkhe M M,et al.Synthesis of 1,1-diaryl ethylenes by Cu-catalyzed arene C-H addition to aryl acetylenes[J].Tetrahedron Letters,2009,50(8):893-896.

备注/Memo

备注/Memo:
[收稿日期]2013-08-26 [基金项目]国家自然科学基金(21171133) [作者简介]赵彩霞(1989 —),女,黑龙江牡丹江人,温州大学化学与材料工程学院硕士研究生; 李新华(1969 —),男,山东德州人,温州大学化学与材料工程学院教授,博士.
更新日期/Last Update: 2013-12-20